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22 Tentative assignment of EI fragments of aminoalcohol activators to structures (for molecular masses, m. m. , see Table 7. 19). Mass online tattoo magazine 15, 27, 28, 29, 30, 41, 42, 43, 44, 56, 58, 70, 72, 84, 85, 86: unsaturated and saturated hydrocarbons (even) or hydrocarbon radicals (uneven). Some of these may also belong to N- or O-containing fragments 30 36 38 43 44 45 70 72 CH2NH2 ? ? C2H3NH2 C2H3OH C2H4OH5C2H5NH2 C4H8N azacyclopentane - H C4H10N azacyclopentane + H 74 75 84 85 86 114 118 H3C-NH-C2H4O H3C-NH-C2H4OH C5H10N azacyclohexane - H C5H11N azacyclohexane C4H10N2, piperazine H2C-N(C3H7), H3C-N(C2H4OH)2-H Table 7. 23 Mass online tattoo magazine (m/z>200) and relative intensities (italics) of fragments in the EIMS of commercial additives (from Yoshikawa e t a l , 10. 2. 1) Substancea 1 2 3 4 5 6 7 8 9 10 Trade or chemical name BHT DLTDP Irganox 1010 Irganox 1076 Topanol CA Antioxidant 2246 Santowhite Tinuvin 327 erucamide oleic amide M (g/mol) 220 514 1176 530 544 340 382 357 337 281 Mass online tattoo magazine {mlz) relative intensities (strongest one: = 100) 205 100 346 100 309 100 530 100 339 100 340 100 339 100 342 100 337 100 281 100 220 25 329 95 323 95 219 89 340 25 284 51 340 25 344 33 320 33 225 37 206 15 514 62 342 66 515 39 205 24 341 30 382 75 357 28 338 28 264 33 273 40 219 50 225 8 544 3 283 26 341 5 343 25 294 25 238 25 347 37 410 44 277 6 353 2 269 8 323 3 359 20 240 10 212 25 330 35 425 44 203 3 323 2 228 6 383 2 358 5 212 5 226 25 241 30 227 33 210 1 206 2 227 3 367 2 287 4 226 4 253 22 300 28 355 33 217 1 309 I 255 I 309 1 309 3 521 3 210 10 515 27 292 25 262 J 365 1 265 1 203 1 315 3 254 3 220 10 441 3 351 25 307 I 545 1 325 1 219 I 301 2 210 2 222 10 a l=2,6-di-?-butyl-p-cresol, 2=dilaurylthiodipropionate, 3=pentaerythritol tetraester of 2-(4-hydroxy-3,5-di-f-find a tattoo artist)propionic acid, 4=octadecyl-3-(3,5-di-f-butyl-4-hydroxyphenyl)propionate, 5=l,l,3-fn5(2-jin kazama tatoo-4-hydroxy-5-t-find a tattoo artist)butane, 6=2,2'-jin kazama tatooene-frzs(4-jin kazama tatoo-6-^butylphenol), 7=4,4 '-butylidene-fezs(3-jin kazama tatoo-6-t-butylphenol), 8=2-(2-hydroxy-3,5-di-^-find a tattoo artist)-5-chlorobenzotriazole Table 7.
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